Material Safety Data Sheet

Finico Danish Oil    

                             

Section 1- PRODUCT IDENTIFICATION          

Product identifier/Trade name:

DANISH OIL

Product code/Internal Identification:

None

Product use/Description:

Paint

Product chemical name:

Mixture

Chemical family:

N/Ap

MSDS preparation/review date:

December 2, 2015

Supplier identifier:  

Produits Tembi, 797 ave Granada,

Rouyn-Noranda Qc, J9X 7B3,        

Telephone: 1 888 797-4344,

Fax: 819 797-8841

Manufacturer identifier:

Same as supplier.

Emergency phone number:

Canutec 613 996-6666.

WHMIS Classification: D2B

B3 – Combustible liquid

D2B – Toxic material with other effects

Section 2- HAZARDS IDENTIFICATION

Emergency Overview

CAUTION!  Combustible liquid. May cause respiratory and digestive tract, eye and skin irritations.

*POTENTIAL HEALTH EFFECTS*

Primary entry route(s): Skin contact, skin absorption, eye contact, ingestion and inhalation.

Effects of short-term (acute) exposure:

Inhalation: May cause mild to moderate irritations to respiratory tract. Vapors may cause nausea, headache and weakness. May cause central nervous system depression. Symptoms may include headache, dizziness, drowsiness, incoordination and unconsciousness.

Skin:  Direct skin contact may cause mild to moderate irritations.

Eye:  Direct eye contact may cause mild to moderate eye irritations. Symptoms may include redness, stinging, tearing and pain.

Ingestion: Ingestion may cause mild to moderate irritations to the mouth, throat and stomach. Aspiration hazard. Swallowing or vomiting of the liquid may cause aspiration (breathing) into the lungs.

Effects of long-term (chronic) exposure:

Refer to Section 11, Toxicological Information, for further information.

Other important hazards:

Refer to Section 11, Toxicological Information, for further information.

Section 3- CHEMICAL COMPOSITION / HAZARDOUS INGREDIENTS

Hazardous Ingredients

CAS #  

% (weight)

LD50 (route, species)

LC50 (species)

Kerosene, hydrotreated

64742-47-8  

40-70

N/Av  

N/Av

Linseed oil

8001-26-1

10-30

N/Av

N/Av

Soybean oil

8001-22-7

10-30

N/Av

N/Av

Rosin ester resin

N/Av

10-30

N/Av

N/Av

1,2,4-Trimethylbenzene

95-63-6

0.1-1.0

5 g/kg (oral, rat)

18000 mg/m3 (rat) 4 hrs

 

                                                                               

Section 4- FIRST AID MEASURES

Inhalation:

Remove source of contamination or have victim move to fresh air. If not breathing, give artificial respiration. Obtain medical attention immediately.

Skin contact:

Wash contaminated area with running water for at least 15-20 minutes, while removing contaminated clothing. Obtain medical attention.  Launder contaminated clothing before re-use.  

Eye contact:

Immediately flush the contaminated eye(s) with gently flowing water for at least 15-20 minutes. Obtain medical attention..

Ingestion:

NEVER give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing. Rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink two glasses of water. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Repeat administration of water. Obtain medical attention immediately.

Section 5- FIRE FIGHTING MEASURES

Fire hazards/conditions of flammability:

Combustible liquid under normal handling conditions. Materials such as rags used with this product may begin to burn by themselves. After use, put rags in water or lay flat to dry, then discard.

Flash point (Method):

40.5°C (105°F)

Lower flammable limit (% by volume):

N/Av

Upper flammable limit (% by volume):

N/Av

Sensitivity to mechanical impact:

Probably not sensitive.

Sensitivity to static discharge:

Probably not sensitive.

Auto-ignition temperature:

N/Av

Suitable extinguishing media:

Carbon dioxide, dry chemical powder and appropriate foam.

Special fire-fighting procedures/equipment:

During a fire, irritating/toxic smoke and fumes may be generated. Do not enter fire area without proper protection.  Firefighters should wear proper protective equipment and self-contained breathing apparatus with full facepiece.  Shield personnel to protect from venting, rupturing or bursting cans.  Move containers from fire area if it can be done without risk.  Water spray may be useful in cooling equipment and cans exposed to heat and flame.

Hazardous combustion products: Carbon oxides and other irritating fumes and smoke.

Section 6- ACCIDENTAL RELEASE MEASURES

Personal precautions:

Restrict access to area until completion of clean-up. Ensure clean-up is conducted by trained personnel only. Remove all ignition sources. Remove or isolate flammable and combustible materials. All persons dealing with clean-up should wear the appropriate protective equipment (See Section 8).

Spill response/Cleanup:

Ventilate area of release. Eliminate all sources of ignition. Stop the leak if it can be done safely. Contain and absorb any spilled liquid concentrate with inert absorbent material, then place material into a container for later disposal (see Section 13). Contaminated absorbent material may pose the same hazards as the spilled product. Notify the appropriate authorities as required.

Environmental precautions:

Confine spill, preventing it from entering sewer lines or waterways. Dispose of as per local, state and federal regulations.

Section 7- HANDLING AND STORAGE

Safe handling procedures:

Before handling, it is very important that engineering controls are operating, and that protective equipment requirements and personal hygiene measures are being followed. People working with this chemical should be properly trained regarding its hazards and its safe use. Do not use near welding operations, flames or hot surfaces. Inspect containers for leaks before handling. Label containers appropriately. Ensure proper ventilation. Avoid breathing dusts, vapours or mists.  Avoid contact with eyes, skin and clothing.  Keep away from heat, sparks and flame.  Avoid generating high concentrations of dusts, vapours or mists.  Keep away from incompatible materials such as strong oxidizing materials. Keep containers closed when not in use. Empty containers are always dangerous. Assume that empty containers contain residues which are hazardous.

Storage requirements:

Store in a cool, dry, well-ventilated area out of direct sunlight, away from heat and ignition sources. Store away from incompatible materials. Inspect all incoming containers to make sure they are properly labelled and not damaged.  Storage area should be clearly identified, clear of obstruction and accessible only to trained personnel. Inspect periodically for damage or leaks.

Incompatible materials:

STRONG OXIDIZING MATERIALS, …

Section 8- EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure limits:

There is no available data for the product. See below for individual ingredient exposure limits.

Ingredient  

OSHA

PEL  

ACGIH

  TLV

TWA

STEL

 TWA

 STEL

Kerosene, hydrotreated

N/Av

N/Av

200 mg/m3

N/Av

Linseed oil

N/Av

N/Av

N/Av

N/Av

Soybean oil

N/Av  

N/Av  

N/Av  

N/Av  

Rosin ester resin

N/Av  

N/Av  

N/Av  

N/Av  

1,2,4-Trimethylbenzene

N/Av  

N/Av  

25 ppm

N/Av  

Engineering controls:

Use under well-ventilated conditions. Local exhaust ventilation system is recommended to maintain concentrations of contaminants below exposure limits.

Respiratory Protection:

Respiratory protection is required if the concentrations are higher than the exposure limits. Use a NIOSH approved respirators if the exposure limits are unknown.

Protective Clothing/Equipment:

Chemically protective gloves (impervious), and other protective clothing to prevent prolonged or repeated skin contact, must be worn during all handling operations. Wear protective chemical splash goggles to prevent mist, vapour and dust from entering the eyes. Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in work area.  

General Hygiene Considerations:

Avoid generating high concentrations of dusts, vapours or mists.  Avoid contact with skin and eyes. Avoid breathing dusts, vapours or mists. Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material. Remove and wash contaminated work clothing before re-use.

Section 9- PHYSICAL AND CHEMICAL PROPERTIES

Physical state, colour and odour:

Colored liquid with a hydrocarbon odour.

Odour threshold:

N/Av

pH :

8,0 ± 0.5

Boiling point:

N/Av

Melting/freezing point:

N/Av

Vapour pressure:

N/Av

Coefficient of oil/water distribution:

N/Av

Solubility in water:

N/Av

Specific gravity or density (water = 1):

0.85

Vapour density (Air = 1):

Heavier than air

Evaporation rate (n-Butyl acetate = 1):

N/Av

% volatile by volume:

N/Av

Section 10- REACTIVITY AND STABILITY DATA

Stability and reactivity:

Stable under the recommended storage and handling conditions prescribed.

Polymerization:

Hazardous polymerization will not occur.

Conditions to avoid:

Incompatible materials (see Section 7). Avoid heat, sparks, direct flame and other ignition sources.

Materials to avoid:

Incompatible materials (see Section 7).

Hazardous decomposition products:

None. Refer to ‘Hazardous combustion products’, Section 5.

Section 11- TOXICOLOGICAL INFORMATION

Toxicological data:

There is no available data for the product itself, only for the ingredients. For more details, refer to Section 3

Carcinogenicity:

No ingredient is listed by IARC, ACGIH, NTP or OSHA as a carcinogen.

Teratogenicity, mutagenicity, other reproductive effects:

N/Av

Skin sensitization:

N/Av

Respiratory tract sensitization:

N/Av

Conditions aggravated by exposure:

N/Av

Synergistic materials:

N/Av

Section 12- ECOLOGICAL INFORMATION

Environmental effects: There is no available data on the product itself.

Important environmental characteristics: N/Av

Aquatic toxicity: N/Av

Section 13- WASTE DISPOSAL

Handling and storage conditions for disposal:

Store material for disposal as indicated in Handling and Storage (Section 7).

Methods of disposal:

Review federal, provincial and local government requirements prior to disposal.

Section 14- TRANSPORTATION INFORMATION

Transportation of Dangerous Goods Regulations (TDGR) :

TDG Classification: UN1263; PAINT; CLASS 3; PG III

Special case: Product can also be shipped as a LIMITED QUANTITY according to TDG Section 1.17.

Section 15- REGULATORY INFORMATION

WHMIS information:

Product is regulated according to the Controlled Product Regulations (CPR) in Canada. Refer to Section 1 for the appropriate WHMIS classification. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and this MSDS contains all the information required by the CPR.

Canadian Environmental Protection Act (CEPA) information: 

The ingredients in this product are listed on the DSL.

United States OSHA information: 

This product is regulated according to OSHA. This MSDS contains all the information required by OSHA.

United States TSCA information:

The ingredients in this product are listed on the TSCA.

Section 16-  OTHER INFORMATION

Prepared by: NSS ENTREPRISE INC. for Tembi Products

Telephone number: 1-888 637-2483

References:

1. Material Safety Data Sheets from manufacturer/supplier.

2. CSST, Répertoire Toxicologique, Les produits, 2012.

3. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2012.

Abbreviations:

ACGIH        American Conference of Governmental Industrial Hygienists

AIHA          American Industrial Hygiene Association

CAS           Chemical Abstract Service

LC              Lethal concentration

LD              Lethal Dosage

IARC          International Agency for Research on Cancer

LIS             Liste intérieure des substances (DSL)

NIOSH       National Institute for Occupational Safety and Health

NTP           National Toxicology Program (U.S.A.)

OSHA        Occupational Safety and Health Administration (U.S.A.)

PEL           Permissible Exposure Limit

SIMDUT     Système d’information sur les matières dangereuses utilisées au travail

STEL         Short-term Exposure Limit

TLV           Threshold Limit Value

TSCA        Toxic Substances Control Act

TWA         Time Weighted Average

USEPA     United States Environmental Protection Agency

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. End of the MSDS